Kostiantyn Marichev
Assistant Professor Chemistry- Education
B.S. in Chemistry, Donetsk National University, Ukraine, 2007.
M.S. in Chemistry, Donetsk National University, Ukraine, 2008.
Ph.D. in Organic Chemistry, The L. M. Litvinenko Institute of Physical Organic and Coal Chemistry (IPOCC), National Academy of Sciences of Ukraine, Donetsk, Ukraine (2008 – 2013). Synthesis and Properties of New Types of Carbenoids of Azole Series. Macrocyclic and Polymeric Systems. Advisor: Prof. Nikolai. I. Korotkikh
Postdoctoral Research Associate. University of Nebraska–Lincoln, Department of Chemistry, Prof. James M. Takacs group (Catalytic Asymmetric Hydroboration, Site-Selective Reactions, Supramolecular Catalysis, Hydrogen Auto-Transfer in Catalytic Amination of Alcohols). 2013 – 2015.
Postdoctoral Research Fellow. University of Texas at San Antonio, Department of Chemistry, Prof. Michael P. Doyle group) (Diazo Chemistry, Design and Development of Chiral Catalysts, Chemistry of Heterocycles, Cycloaddition Chemistry). 2016 – 2020.
- Specializations
Synthetic Organic Chemistry; Catalysis; Organometallic Chemistry; Asymmetric Reactions and Synthesis; Supramolecular Catalysis; Site-Selective Reactions; Chemistry of Heterocycles; N-Heterocyclic Carbenes (NHCs) and Metal Complexes of NHCs.
- Biography
- Publications
Full List of Publications on Google Scholar
1. Wang, R.; Marichev, K. O.; Dong, K.; Jensen, J. A.; Doyle, M. P. Chiral 3-Acylglutaric Acid Derivatives from Strain-Induced Nucleophilic Retro-Claisen Ring-Opening Reactions. J. Org. Chem. 2020, 85, 9475–9490.
https://pubs.acs.org/doi/abs/10.1021/acs.joc.0c011762. Marichev, K. O.; Dong, K.; Massey, L. A.; Deng, Y.; De Angelis, L.; Wang, K.; Arman, H.; Doyle, M. P. Chiral donor−acceptor azetines as powerful reactants for synthesis of amino acid derivatives. Nature Commun. 2019, 10, 5328. DOI: 1038/s41467-019-13326-8.
Behind the Paper Post in Nature Research Community.
Highlighted in Synfacts 2020, 16 (04), 0480. DOI: 10.1055/s-0039-1690061.3. Marichev, K. O.; Wang, K.; Dong, K.; Greco, N.; Massey, L. A.; Deng, Y.; Arman, H.; Doyle, M. P. Synthesis of Chiral Tetrasubstituted Azetidines from Donor-Acceptor Azetines via Asymmetric Copper(I)-Catalyzed Imido-Ylide [3+1]-Cycloaddition with Metallo-Enolcarbenes. Angew. Chem. Int. Ed. 2019, 58, 16188–16192. DOI: 10.1002/anie.201909929.
Highlighted in Synfacts 2019, 15 (12), 1393. DOI: 10.1055/s-0039-16911114. Dong, K.; Marichev, K. O.; Doyle, M. P. The Role of Donor-Acceptor Cyclopropenes in Metal Carbene Reactions. Conversion of E-Substituted Enoldiazoacetates to Z-Substituted Metallo-Enolcarbenes. Organometallics 2019, 38, 4043–4050. DOI: 1021/acs.organomet.9b00427
(Special Issue: Asymmetric Synthesis Enabled by Organometallic Complexes).
https://pubs.acs.org/doi/abs/10.1021/acs.organomet.9b004275. Dong, K.; Marichev, K. O.; Xu, X.; Doyle, M. P. High Stereocontrol in the Preparation of Silyl-Protected γ-Substituted Enoldiazoacetates. Synlett 2019, 30, 1457–1461.
DOI: 10.1055/s-0037-16118656. Marichev, K. O.; Doyle, M. P. Catalytic asymmetric cycloaddition reactions of enoldiazo compounds. Org. Biomol. Chem. 2019, 17, 4183 – 4195.
https://pubs.rsc.org/en/content/articlelanding/2019/ob/c9ob00478e/7. Adly, F. G.; Marichev, K. O.; Jensen, J. A.; Arman, H.; Doyle, M. P. Enoldiazosulfones for Highly Enantioselective [3 + 3]-Cycloaddition with Nitrones Catalyzed by Copper(I) with Chiral BOX Ligands. Org. Lett. 2019, 21, 40 – 44.
https://pubs.acs.org/doi/10.1021/acs.orglett.8b034218. Marichev, K. O.; Adly, F. G.; Carranco, A. M.; Garcia, E. C.; Arman, H.; Doyle, M. P. Catalyst Choice for Highly Enantioselective [3 + 3]-Cycloaddition of Enoldiazocarbonyl Compounds. ACS Catal. 2018, 8, 10392 – 10400. (DOI: 1021/acscatal.8b03391).
9. Marichev, K. O.; Wang, Y.; Carranco, A. M.; Garcia, E. C.; Yu, Z.-X.; Doyle, M. P. Rhodium(II)-Catalysed Generation of Cycloprop-1-en-1-yl Ketones and Their Rearrangement to 5-Aryl-2-siloxyfurans. Commun. 2018, 54, 9513 – 9516. (DOI: 10.1039/C8CC05623D).
10. Marichev, K. O.; Patil, S. A.; Bugarin, A. Recent Advances in the Synthesis, Structural Diversity, and Applications of Mesoionic 1,2,3-Triazol-5-ylidene Metal Complexes. Tetrahedron 2018, 74, 2523 – 2546.
https://www.sciencedirect.com/science/article/pii/S004040201830381811. Marichev, K. O.; Garcia, E. C.; Bhowmick, K. C.; Wherritt, D. J.; Arman, H.; Doyle, M. P. Highly Selective Acylation of Polyamines and Aminoglycosides by 5-Acyl-5-phenyl-1,5-dihydro-4H-pyrazol-4-ones. Chem. Sci. 2017, 8, 7152 – 7159.
https://pubs.rsc.org/en/content/articlelanding/2017/sc/c7sc03184j12. Marichev, K. A.; Korotkikh, N. I.; Cowley, A. H.; Saberov, V. Sh.; Glinyanaya, N. V.; Rayenko, G. F.; Shvaika, O. P. Highly Efficient Carbene and Polycarbene Catalysis of the Transesterification Reaction. Arkivoc 2017 , IV, 365 – 376.
http://www.arkat-usa.org/get-file/60446/13. Marichev, K. O.; Ramey, J. T.; Arman, H.; Doyle, M. P. Highly Regio-, Diastereo-, and Enantioselective Rhodium-Catalyzed Intramolecular Cyclopropanation of (Z)-1,3-Dienyl Aryldiazoacetates. Org. Lett. 2017, 19, 1306 – 1309.
http://pubs.acs.org/doi/abs/10.1021/acs.orglett.7b0011914. Qiu, H.; Deng, Y.; Marichev, K. O.; Doyle, M. P. Diverse Pathways in Catalytic Reactions of Propargyl Aryldiazoacetates: Selectivity between Three Reaction Sites. J. Org. Chem. 2017, 82, 1584 – 1590.
http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b0277015. Marichev, K. O.; Qiu, H.; Offield, A. C.; Arman, H.; Doyle, M. P. Catalyst-Free Rearrangement of Allenyl Aryldiazoacetates into 1,5-Dihydro-4H-pyrazol-4-ones. J. Org. Chem. 2016, 81, 9235 – 9246.
http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b0183316. Marichev, K. O.; Takacs, J. M. Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology. ACS Catal. 2016, 6, 2205 – 2210.
http://pubs.acs.org/doi/abs/10.1021/acscatal.6b00175
Highlighted: D. F. Taber, Org. Chem. Highlights 2017, January 30.
https://www.organic-chemistry.org/Highlights/2017/30January.shtm